Abstract This research was an attempt to use the currently available activity coefficient methods with universal sets of parameters to simultaneously predict ternary liquid-liquid equilibrium data. The focus of this research was to calculate phase equilibrium data within fair error using set of Parameters obtained from the above-mentioned models. The significance of this work is to study the liquid-liquid phase equilibrium of the ternary system at several temperatures and to test the capability of the various equilibrium models to correlate these data. A series of liquid-liquid equilibrium measurements were performed by changing the composition of the mixture.The prepared mixtures were placed in the extraction vessel and stirred for 2 h and then left to settle for 4 h. Samples were taken by a syringe from both the upper phase and lower layers. Both phases were analyzed using gas chromatography equipped. Liquid-liquid equilibrium for the ternary system acetonitrile + benzene + n-heptane was measured at 298,313,333 K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the two models. The UNIQUAC equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. NRTL models satisfactorily predicted the equilibrium compositions. In each of the mentioned the ternary system, the calculated and experimental data were compared. The root mean square deviation (RMSD) between the observed and calculated mole percent for NRTL, UNIQUAC was 1.44%, 1.35% for acetonitrile + benzene + n-heptane
عماد الدين محمد الزغداني (2014)

Abstract 1. The experimental viscosities densities measured with Anton Paar SVM 3000 equipment, and refractive indices measured with Refractive Meter equipment, corresponding values of excess molar volumes (VE ), deviations in viscosity (Δμ), deviations in refractive index (ΔnD), excess Gibbs energy (GE), and excess molar enthalpy (HE), for binary, ternary and fourth mixtures of alcohol, ether, and n-alkanes. 2.Used for the calibration experimental from paper [7] were the mixture for the binary system (tert butyl alcohol + ethanol ), we had good result and ADD% for densities, viscosities and refractive indices were 0.1657 %, 0.4846 %, and 0.033545 % respectively. 3.Data of binary mixture were fitted to a Redlich-Kister's The choice of the proper number of coefficients (p), was based on the standard deviations, and the F-test as criterion of goodness with an error lower that 1% see. 4.Data of ternary and fourth mixture were correlated by Cibulka equation were determined with the optimization algorithm similar to that for the binary parameters the σ values was less than 0.05%. 5.The experimental viscosities densities and refractive indices were positive and decrease with increase temperature for all tables for binary ternary and fourth mixtures. 6.Excess molar volumes (VE), was negative value for all binary system, Deviations in viscosity (∆µ), negative value, but at system (n-hexane + n-heptane), maximum positive and minimum with negative value, Deviations in Refractive Index (ΔnD), was were positive for all binary mixtures, Excess Gibbs Energy was negative for all binary ,but maximum positive and minimum with negative value just at system (n-hexane + n-heptane). 7.Excess properties for ternary mixture negative and positive value. 8.Excess properties for fourth mixture negative value.
سهير المبروك دربال (2009)

استخدام المواد المركبة في التطبيقات الصناعية نمى بشكل سريع وذلك لمميزاته المناسبة التي تشمل ارتفاع نسب المقاومة والمتانة بالنسبة للوزن , وقد أصبحت المواد المركبة بديل المواد المعدنية في العديد من التطبيقات. المواد الثيرموبلاستيكية المركبة تم دراستها في هذه الرسالة حيث استعمل البولي اثيلين كقالب ودعم بإضافة ألياف الزجاج بنسب مختلفة ( 10% , 20% , 30% ) , وتم دراسة تأثير إضافة ألياف الزجاج على الخواص الميكانيكية للعينات. تم الحصول على العينات المركبة باستخدام جهاز البثق وإجراء التجارب لتقيم جريان المنصهر عند درجات الحرارة العالية حيث لاحظنا زيادة الجريان بزيادة الضغط . كما تم تطوير علاقات رياضية لتمثيل علاقات الإجهاد – الانفعال للعينات المركبة المتحصل عليها ,تم الحصول على ثوابت هذه العلاقات الرياضية. كما تم دراسة علاقات زمن الانهيارات للعينات المركبة , وتم تحسين طاقة الكسر للمواد المركبة التي تؤخر من ظاهرة الانهيار. إضافة ألياف الزجاج أدى إلى زيادة زمن الانهيار وتقليل طاقة الكسر. Abstract The use of composite materials in industry applications has grown rapidly, owing to their favorable characteristics, including high strength and stiffness to weight ratios, composite materials have been considered replacement of metals in numerous structural applications.Thermoplastic composite was studied in this thesis where high density polyethylene is used as a matrix and reinforced with different percentages of fiber glass ranging from (10%, 20%, 30%). The influence of addition of fibreglass on mechanical and thermal properties was studied. A pilot plant extruder is used to prepare the needed samples, where experimental investigation is carried out to evaluate the melt flow and the impact behaviour of the melt mixture at high temperature in the extruder. The flow rate increased by increased pressure. A mathematical correlation was developed to represent the stress – strain correlations of the composites used in this work. The combined model would be able to predict the creep, relaxation and recovery of composite materials, the constants of the model was obtained in area where the retardation effect is dominating. Time to failure correlation with stress was studied for the prepared composite material and mathematical correlation is established. The energy absorbed at fracture is improved for the composite material leading to a considerable delay in failure phenomenon. When added fibreglass led to increase time to failure and decrease energy of fracture.
ابتسام خليفة ابولجام (2008)