Abstract Cement kiln dust is a major by product in cement manufacture. Methods of disposal, handling, treatment and reuses are a major factors in optimization of a certain cement plant. This thesis concentrates on the uses of cement kiln dust of souk Al Kamees cement plant as Soil amendment and as an adsorpent of Fe, Zn and lead results from sand. The major objectives of these treatments are environmental rather than economical to reduce the landfill disposal of CKD which is major problem in cement industry. CKD is used in agricultural soil amendment.CKD in Souk Alkamees consists primarily of calcium carbonate and silence dioxide, the alkaline by pass process contains highest amount of calcium oxide and lowest loss on ignation [LOI] which become a beneficial for CKD use as a soil amendment to the sand for many especial agricultural products such as potatoes, …etc. This thesis concentrates on the uses of CKD as an adsorbent to remove heavy metals such as Fe, Zn, and Pb from soil. Adsorption column is used to perform the work. Experimental setup discussed in the thesis is used using cement kiln dust as an adsorbent for removal of heavy metals from soil. The major result is to simulate the physical behavior of the process using conventional isotherms available in literature, Langmuir, Freandlish and Drachsal isotherm models have been found to simulate the data with good agreement with experimental work. Characterization of the CKD is made after dehydration process at 150C for 24 hrs. X ray fluorescent equipment is used and the results are reported in the thesis.
محمد محمود الشاهري (2015)

Abstract Recently more than 150 million tonnes of plastics were produced in the world. On the one hand, the consumption and production of polymers are increasing, on the other hand as landfill and incineration become more expensive and less accepted .The increasing amount of polymer wastes from them generates further mainly environmental problems. The recycling of plastic wastes is gaining increasing importance. Pyrolysis is one promising method for the treatment of mixed and contaminated plastic wastes. In this way the plastic wastes are converted into fuels or other valuable feedstock for the petrochemical industry. In present work catalytic cracking of waste plastics blend with HGO [Libyan gas oil supplied by the Zawia Oil Refinery Company boils in the range of 275-375Cº] was investigated using H-ZSM5and H-BETA. Reaction systems that were studied included high density polyethylene HDPE and polypropylene blend with HGO, reactions were carried out in one litre micro autoclave reactor under different conditions of weight, temperature and type of catalyst, The optimum conditions were 2.5% catalyst by weight of total feed stock, one hour, atmospheric presser and three temperatures selected 400Cº, 425Cº and 450Cº. The product distribution for the system [plastics and HGO] provided some good results high yield of liquid [gasoline] up to 210Cº, gases and small amount of heavy oils. Some analysis was used to qualify and quantify the product. The results from GC.MS analysis showed that the yield of gasoline (c5-c12) over H-ZSM5 higher than H-BETA. In case of 5%PP, 15%HDPE and 80%HGO over H-ZSM5 at 450Cº, 96% total conversion achieved. The result from TGA in the same case is 15% by weight. Also the theoretical calculations to quantify the produced gases after burring of waste plastic in rotary kiln reactor have been evaluated. it is found that the suitable ratio of CO:H2 to produce methanol is 7:1
بسمة محمود التونسي (2010)

Abstract This research was an attempt to use the currently available activity coefficient methods with universal sets of parameters to simultaneously predict ternary liquid-liquid equilibrium data. The focus of this research was to calculate phase equilibrium data within fair error using set of Parameters obtained from the above-mentioned models. The significance of this work is to study the liquid-liquid phase equilibrium of the ternary system at several temperatures and to test the capability of the various equilibrium models to correlate these data. A series of liquid-liquid equilibrium measurements were performed by changing the composition of the mixture.The prepared mixtures were placed in the extraction vessel and stirred for 2 h and then left to settle for 4 h. Samples were taken by a syringe from both the upper phase and lower layers. Both phases were analyzed using gas chromatography equipped. Liquid-liquid equilibrium for the ternary system acetonitrile + benzene + n-heptane was measured at 298,313,333 K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the two models. The UNIQUAC equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. NRTL models satisfactorily predicted the equilibrium compositions. In each of the mentioned the ternary system, the calculated and experimental data were compared. The root mean square deviation (RMSD) between the observed and calculated mole percent for NRTL, UNIQUAC was 1.44%, 1.35% for acetonitrile + benzene + n-heptane
عماد الدين محمد الزغداني (2014)