Abstract Here asphaltene precipitation in petroleum reservoirs during natural depletion and miscible gas injection is modeled for two distinct and new methods (polymer solution and Scott-Magat theory). The first model is based on the polymer solution theory, which is a combination of Miller's combinatorial term with a modified residual term of the original Flory-Huggins theory. The second one is based on the Scott Magat theory to represent solid-liquid equilibria. The models has also been coupled with Peng Robinson equation of state (PR EOS) to describe the phase behavior of asphaltene compounds in crude oil and predict the amount of asphaltene precipitation during injection of carbon dioxide for the miscible displacement of asphaltic crudes. The model treats asphaltene within crude oil as a single pseudocomponent represented by an average molecular weight and molar volume and solubility parameter . The results of both models show an acceptable and good agreement between the real data (field and experimental) and those of the models. As it can be seen from the obtained results of those of the two models, it seems that application of the lattice or polymer solution theories (based on The Miller's combinatorial term) could give better results that are more close to real data.
وداد بلعيد حميدات (2009)

Abstract This research was an attempt to use the currently available activity coefficient methods with universal sets of parameters to simultaneously predict ternary liquid-liquid equilibrium data. The focus of this research was to calculate phase equilibrium data within fair error using set of Parameters obtained from the above-mentioned models. The significance of this work is to study the liquid-liquid phase equilibrium of the ternary system at several temperatures and to test the capability of the various equilibrium models to correlate these data. A series of liquid-liquid equilibrium measurements were performed by changing the composition of the mixture.The prepared mixtures were placed in the extraction vessel and stirred for 2 h and then left to settle for 4 h. Samples were taken by a syringe from both the upper phase and lower layers. Both phases were analyzed using gas chromatography equipped. Liquid-liquid equilibrium for the ternary system acetonitrile + benzene + n-heptane was measured at 298,313,333 K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the two models. The UNIQUAC equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. NRTL models satisfactorily predicted the equilibrium compositions. In each of the mentioned the ternary system, the calculated and experimental data were compared. The root mean square deviation (RMSD) between the observed and calculated mole percent for NRTL, UNIQUAC was 1.44%, 1.35% for acetonitrile + benzene + n-heptane
عماد الدين محمد الزغداني (2014)

Abstract Deposition of undesirable materials on water wall side of boiler tube that are operated under forced circulation boiling conditions can cause serious trouble in steam boilers. The present study is concerned with the scaling characteristics of water in the boilers. The effects of heat flux and water velocity were evaluated for water having a total hardness and calcium hardness in the range (TH= 380 to 390 ppm asCaCO3 ) and(CaH= 250 to 298 ppm asCaCO3) respectively. The heat flux ranged from (1.05 x 105) to and water velocity in a vertical annular test section range from 0.51 to 0.75 m/sec (1.67 to 2.5 ft/sec) . The test section consisted of an annular duct 0.050 m (2.0-in) O.D. and 0.033 m (1.33-in ) I.D. A 0.30 m (12-in) section of the concentric core of the annulus was electrically heated. Hot water at 97.0 (370.1) was circulated through the annulus where boiling occurred on the heated section. The temperature range at the Surface of heated section in the annulus was from (105 - 118 ). The results of five tests are reported in this study. The fouling resistance vr. time curves reached an asymptotic value and the average of fouling resistance for Runs (1-5) had been plotted. Chemical analysis of scale deposits indcated that Calcium carbonate and Silica were the man Constituents. At constant surface temperature an increase in velocity from 0.51 to 0.75 m/sec (1.67 -2.5 ft/sec), caused about a 20 percent reduction in the asymptotic fouling resistance.
عادل محمد شنقير (2008)